Search results for "Structural characterisation"
showing 2 items of 2 documents
Microstructure and shear strength evolution of a lime-treated clay for use in road construction
2020
The results of a comprehensive experimental programme are presented for assessing the long-term microstructural modifications and evaluating the effects of microstructural rearrangement on the stress–strain behaviour of a lime-treated high-plasticity clay for road embankments. The stress–strain behaviour at different lime content and curing time was investigated by means of direct shear tests; microstructural analyses were carried out combining Scanning Electron Microscope observations and Mercury Intrusion Porosimetry tests. The results show that the stress–strain behaviour of treated clay is strongly dilatant with a high peak of strength, which increases with time and lime content. Furthe…
Detection and localisation of disulphide bonds in a synthetic peptide reproducing the sequence 1-30 of Par j 1.0101 by electrospray ionisation mass s…
2001
The structural characterisation of a synthetic peptide reproducing the sequence 1–30 of Par j 1.0101, a major allergenic protein present in the pollen of Parietaria judaica, by combined use of chemical and enzymatic cleavage, reversed-phase high-performance liquid chromatography (RP-HPLC) and electrospray ionisation mass spectrometry (ESI-MS), is described. Direct ESI-MS of the synthetic peptide after reaction with methyl iodide showed that the product is a mixture of two peptides: one form in which two out of the four cysteine residues present in the sequence are oxidised and a minor amount of another form in which all the cysteines are fully reduced. It was ascertained, using the combined…